University of Louisville

Department of Chemistry
Mailing address:

Department of Chemistry
University of Louisville
2320 South Brook Street
Louisville, KY 40292

Phone Numbers:
(502) 852-6798 (phone)
(502) 852-8149 (fax)
cag
Craig A. Grapperhaus
Associate Professor

Inorganic Chemistry
Metal-thiolates, ligand-based reactivity,
inorganic synthesis

Phone: (502) 852-5932
grapperhaus@louisville.edu


B.S.
1994
Southern Illinois University at Edwardsville
Ph.D.
1998
Texas A&M University
1998-2000
Alexander von Humboldt Postdoctoral Fellow
Max-Planck Institut für Strahlenchemie
Recent Publications
    Carbon-Sulfur Bond Formation between a Ruthenium-Coordinated Thiyl Radical and Methyl Ketones.
    Poturovic, S.; Mashuta, M. S.; Grapperhaus, C. A.
    Angew. Chem., Int. Ed. Engl., 2005, 44, 1883-1887

    Structural Comparison of Alkylated Derivatives of (bmmp-dmed)Ni and (bmmp-dmed)Zn.
    Grapperhaus, C. A.; Mullins, C. S.; Mashuta, M. S.
    Inorg. Chim. Acta. 2005, 358, 623-632

    Template Synthesis of N2S and N3S Chelates via Alkylation of bis(2-aminoethanethiolato)Ni: Sulfur- and Nitrogen-Centered Alkylations.
    Grapperhaus, C. A.; Kreso, M.; Burkhardt, G. A.; Roddy, J. V. F.;
    Mashuta, M. S.
    Inorg. Chim. Acta. 2005, 358, 123-130

    Electrochemical Investigations of [tris(2-diphenylphosphino-thia- phenolato)-ruthenium(II)]-¬ Reveal Metal- and Ligand-Centered Events: Radical, Reactivity, and Rate.
    Grapperhaus, C. A.; Poturovic, S.
    Inorg. Chem., 2004, 43, 3292-3298

    Synthesis and Oxygenation of a Nickel(II) and Zinc(II) Dithiolate: An Experimental and Theoretical Comparison
    Grapperhaus, C. A.; Mullins, C. S.; Kozlowski, P. M.; Mashuta, M. S.
    Inorg. Chem., 2004, 43, 2859-2866

    Structural, Spectroscopic and Computational Study of an Octahedral, Non-heme {Fe-NO}6,7,8 Series: [Fe(NO)(cyclam-ac)]2+,1+,0
    Serres, R. G.; Grapperhaus, C. A.; Bothe, E.; Bill, E.; Weyhermüller, T.; Neese, F.; Wieghardt, K.
    J. Am. Chem. Soc., 2004, 126, 5138-5153

    Hydrogen-Bond Networks in the Mono- and Diprotonated Cyclic Diamine [9]aneN2S
    Grapperhaus, C. A.; Li, M.; Gibson, E. R.; Mashuta, M. S.
    J. Chem. Crystallogr., 2004, 34, 5-11

    Synthesis and Characterization of N2S3X-Fe Models of Iron-Containing Nitrile Hydratase
    Grapperhaus, C. A.; Li, M.; Patra, A. K.; Poturovic, S.; Kozlowski, P. M.; Zgierski, M. Z. Mashuta, M. S.
    Inorg. Chem., 2003, 42, 4382-4388