Link to Older and Broader Publications
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Yang, Y.; Miraghaee, S.; Pace, R.; Umemoto, T.; Hammond, G. B. Angew. Chem. Int. Ed. 2023, 62, e202306095. |
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Self-Sustaining Fluorination of Active Methylene Compounds and High-Yielding Fluorination of Highly Basic Aryl and Alkenyl Lithium Species with a Sterically Hindered N-Fluorosulfonamide Reagent Yang, Y.; Hammond, G. B.; Umemoto, T. Angew. Chem. Int. Ed. 2022, 61, e202211688.
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Synthesis and application of S-(trifluoromethyl)-2,8-bis(trifluoromethoxy)dibenzothiophenium triflate (Umemoto reagent IV) Mudshinge, S.; Hammond, G. B.; Umemoto, T. J. Fluorine Chem. 2022, 261-262, 110015. |
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Gold(I/III)-Catalyzed Trifluoromethylthiolation and Trifluoromethylselenolation of Organohalides Mudshinge, S.; Yang, Y.; Xu, B.; Hammond, G. B.; Lu, Z. Angew. Chem. Int. Ed. 2022, 61, e202115687. Hot Paper |
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Liu, S., Meng, L., Zeng, X., Hammond, G. B., Xu, B. Chin. J. Chem. 2021, 39, 913-917.
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Aromatic Ketone-Catalyzed Photochemical Synthesis of Imidazo-isoquinolinone Derivatives Zhao, B., Hammond, G. B., Xu, B. J. Org. Chem. 2021, 86, 12851−12861. |
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Zhao, B., Hammond, G. B., Xu, B. Tetrahedron Lett 2021, 82, 153376-153382.
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Unbalanced-Ion-Pair-Catalyzed Nucleophilic Fluorination Using Potassium Fluoride Li, W.; Lu, Z.; Hammond, G. B.; Xu, B. Org. Lett. 2021, 23, 9640–9644.
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Development of N-F fluorinating agents and their fluorinations: Historical perspective Umemoto, T.; Yang, Y.; Hammond, G. B. Beilstein J. Org. Chem.2021, 17, 1752–1813.
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Lu, Z.; Kumon, T.; Hammond, G. B.; Umemoto, T. Angew. Chem. Int. Ed. 2021,60, 16171-16177.
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T. Li, G. B. Hammond, B. Xu. Chem Eur. J. 2021, 27, 9737-9741.
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Optimization of Catalysts and Conditions in Gold(I) Catalysis—Counterion and Additive Effects Lu, Z.; Li, T.; Mudshinge, S.; Xu, B.; Hammond, G. B.Chem.Rev. 2021, 121, 8452-8477.
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Transition State Expansion: A Quantitative Model for Counterion Effects in Ionic Reactions Han, J.; Lu, Z.; Hammond, G. B.; Xu, B. iScience. 2020, 23, 101593.
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Revisiting the role of acids and hydrogen bond acceptors in enamine formation Lu, Z.; Hammond, G. B.; Xu, B. Org. Biomol. Chem. 2020, 18, 6849 - 6852.
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HCl·DMPU-assisted One-pot and Metal-free Conversion of Aldehydes to Nitriles Mudshinge, S.; Potnis, C.; Xu, B.; Hammond, G. B.Green Chem., 2020, 22, 4161-4164. |
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Base-Promoted Radical Azofluoromethylation of Unactivated Alkenes Lu, Z.; Hennis, O.; Gentry, J.; Xu, B.; Hammond, G. B. Org. Lett. 2020, 22, 4383–4388.
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Regio- and Stereoselective Synthesis of 1,2-Dihaloalkenes Using In-Situ-Generated ICl, IBr, BrCl, I2, and Br2 Zeng, X.; Liu, S.; Yang, Y.; Yang, Y.; Hammond, G. B.; Xu, B. Chem 2020,6, 1018-1031 |
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Angnes, R. A.; Potnis, C.; Liang, S.; Correia, C. R. D.; Hammond, G. B. J. Org. Chem. 2020,85, 4153-4164. |
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Photoredox catalyzed C(sp3)C(sp) coupling of dihydropyridines and alkynylbenziodoxolones Liang, S.; Angnes, R. A.; Potnis, C. S.; Hammond, G. B. Tetrahedron Lett. 2019,60, 151230. |
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Synthesis of Alkyl Halides from Aldehydes via Deformylative Halogenation Liang, S.; Kumon, T.; Angnes, R. A.; Sanchez, M.; Xu, B.; Hammond, G. B. Org. Lett. 2019, 21, 3848-3854. |
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Improving Homogeneous Cationic Gold Catalysis through a Mechanism-Based Approach Lu, Z.; Hammond, G. B.; Xu, B. Acc. Chem. Res. 2019, 52, 1275-1288. |
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Homogeneous and Nanoparticle Gold-Catalyzed Hydrothiocyanation of Haloalkynes Zeng, X.; Chen, B.; Lu, Z.; Hammond, G. B.; Xu, B. Org. Lett. 2019. 21, 2772-2776. |
81 | Ebule, R.; Mudshinge, S.; Nantz, M. H.; Mashuta, M. S.; Hammond, G. B.; Xu, B. J. Org. Chem.2019,84, 3249–3259. |
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Solventless and Metal-free Regioselective Hydrofluorination of Functionalized Alkynes and Allenes: An Efficient Protocol for the Synthesis of gem-Difluorides. Lu, Z.; Bajwa, B. S.; Liu, S.; Lee, S.; Hammond, G. B.; Xu, B. Green Chem., 2019, 21, 1467-147.
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Multifaceted ion exchange resin-supported hydrogen fluoride: a path to flow hydrofluorination. Lu, Z.; Bajwa, B. S.; Otome, O. E.; Hammond, G. B.; Xu, B. Green Chem.,2019, 21, 2224-2228 .
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S. Liu, X. Zeng, G. B. Hammond, B. Xu, Adv. Synth. Catal.2018, 360, 3667-3671.
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Angnes, R. A.; Thompson, L. M.; Mashuta, M. S.; Correia, C. R. D.; Hammond, G. B. Adv. Synth. Catal.2018, 360, 3760-3767.
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Metal‐free Chlorothiolation of Alkenes using HCl and Sulfoxides Ebule, R. Hammond, G.; Xu, B.; Eur. J. Org. Chem. 2018, 2018, 4705-4708. |
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Plagiochiline A Inhibits Cytokinetic Abscission and Induces Cell Death Stivers, N.; Islam, A.; Reyes-Reyes, E.; Casson, L.; Aponte, J.; Vaisberg, A.; Hammond, G.; Bates, P. Molecules, 2018,23, 1418.
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Faster and Greener Chemical Reaction Workup Using Silicone Elastomer-Coated Glass Powders Shi, Z.; Hammond, G. B.; Xu, B. ACS Omega 2018, 3, 6748-6756.
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Metal-Free and User-Friendly Regioselective Hydroxyfluorination of Olefins Sedgwick, D. M.; López, I.; Román, R.; Kobayashi, N.; Okoromoba, O. E.; Xu, B.; Hammond, G. B.; Barrio, P.; Fustero, S. Org. Lett. 2018, 20, 2338-2341. |
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Micelle-enabled clean and selective sulfonylation of polyfluoroarenes in water under mild conditions Smith, J. D.; Ansari, T. N.; Andersson, M. P.; Yadagiri, D.; Ibrahim, F.; Liang, S.; Hammond, G. B.; Gallou, F.; Handa, S. Green Chemistry, 2018, 20, 1784-1790. |
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Recyclable cellulose-palladium nanoparticles for clean cross-coupling chemistry Lu, Z.; Jasinski, J. B.; Handa S.; Hammond, G. B. Org. Biomol. Chem. 2018. 16, 2748 - 2752.
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The history and future challenges associated with the hydrogenation of vinyl fluorides Sedgwick, D. M.; Hammond, G. B. J. Fluorine Chem. 2018, 207, 45-58.
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(Radio)Fluoro-Click Reaction Enabled by a Hydrogen Bonding Cluster Zeng, X.; Li, J.; Ng, C. K.; Hammond, G. B.; Xu, B. Angew. Chem., 2018,57, 2924–2928.
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Zeng, X.; Liu, S.; Hammond, G. B.; Xu, B. ACS Catal. 2018,8, 904-909.
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Liang, S.; Hammond, G. B.; Xu, B. Green Chemistry 2018,20, 680-684. |
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Widely Applicable Hydrofluorination of Alkenes via Bifunctional Activation of Hydrogen Fluoride Zhichao Lu, Xiaojun Zeng, Gerald B. Hammond, Bo Xu. J. Am. Chem. Soc., 2017, 139 , 18202–18205.
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Xiaojun Zeng, Shiwen Liu, Zhichao Lu, Gerald B. Hammond, Bo Xu. J. Org. Chem.2017, 82,13179–13187. |
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Predicting Counterion Effects Using a Gold Affinity Index and a Hydrogen Bonding Basicity Index Zhichao Lu,Junbin Han, Otome E. Okoromoba, Naoto Shimizu, Hideki Amii, Cláudio F. Tormena, Gerald B. Hammond, Bo Xu. Org. Lett. 2017, 19, 5848–5851.
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Xiaojun Zeng, Shiwen Liu, Zhichao Lu, Gerald B. Hammond, Bo Xu. Adv. Synth. Cat.. 2017, 359, 4062-4066.
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Chloride-Tolerant Gold(I)-Catalyzed Regioselective Hydrochlorination of Alkynes Rene Ebule, Shengzong Liang, Gerald B. Hammond, Bo Xu. ACS Catal, 2017, 7, 6798–6801.(R.E. and S.L. contributed equally.)
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Hydrogen Bonding: Regulator for Nucleophilic Fluorination Shengzong Liang, Gerald Hammond, Bo Xu. Chem. Eur. J. 2017, 23, 17850-17861. |
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Xiaojun Zeng, Shiwen Liu, Gerald B. Hammond, Bo Xu. Chem. Eur. J. 2017, 23, 11977–11981. |
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Bromofluorination of unsaturated compounds using DMPU/HF as a fluorinating reagent Shengzong LiangFrancis J.BarriosOtome E.Okoromoba, Zofia Hetman, Bo Xu, Gerald B.Hammond. J. Fluorine Chem. 2017, 203, 136-139. |
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HBr–DMPU: The First Aprotic Organic Solution of Hydrogen Bromide Zhou Li, Rene Ebule, Jessica Kostyo, Gerald B. Hammond, Bo Xu. Chem. Eur. J. 2017, 23, 12739-12743. |
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A Chlorinating Reagent Yields Vinyl Chlorides with High Regioselectivity under Heterogeneous Gold Catalysis Shengzong Liang, Rene Ebule, Gerald B. Hammond, Bo Xu. Org. Lett. 2017,19, 4524–4527. (S.L. and R.E. contributed equally.)
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Achieving Regio- and Stereo-Control in the Fluorination of Aziridines under Acidic Conditions Okoromoba E. Otome, Zhou Li, Nicole Robertson, Mark M. Mashuta, Uenifer R. Couto, Cláudio F. Tormena, Bo Xu, Gerald B. Hammond. Chem. Commun. 2016,52, 13353-13356. |
55 |
Simultaneous Rapid Reaction Workup and Catalyst Recovery
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Acidic co-Catalysts in Cationic Gold Catalysis Pablo Barrio, Manish Kumar, Zhichao Lu, Junbin Han, Bo Xu, Gerald Hammond. Chem. Eur. J. 2016, 22, 16410-16414.
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Commercial Supported Gold Nanoparticles Catalyzed Alkyne Hydroamination and Indole Synthesis Shengzong Liang, Luisa Hammon, Bo Xu, Gerald B. Hammond. Adv. Synth. Catal. 2016,358, 3313–3318. |
52 |
Quantification of Hydrogen Fluoride-based Reagents Using a Bifunctional NMR Internal Standard Zhou Li, Gerald B. Hammond, Bo Xu. J. Fluorine Chem.. 2016, 184, 72-74 |
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Au/TiO2 catalyzed reductive amination of aldehydes and ketones using formic acid as reductant Shengzong Liang, Paige Monsen, Gerald B. Hammond, Bo Xu Org. Chem. Front., 2016, 3, 505-509
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Shengzong Liang, Gerald B. Hammond, Bo Xu Chem. Commun., 2016, 52, 6013-6016. This article was featured in Synfacts 2016, 12, 763. |
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Ligand Effects in the Gold Catalyzed Hydration of Alkynes Rene E. Ebule, Deepika Malhotra, Gerald B. Hammond, Bo Xu Adv. Synth. Cat.. 2016, 358, 1478–1481 |
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Revisiting the Influence of Silver in Cationic Gold Catalysis: A Practical Guide Zhichao Lu, Junbin Han, Gerald B. Hammond, Bo Xu Org. Lett. 2015, 17, 4534–4537 |
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Otome E. Okoromoba, Gerald B. Hammond, and Bo Xu Org. Lett., 2015, 17 (16), 3975–3977 |
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Recent synthetic additions to the visible light photoredox catalysis toolbox Ricardo A. Angnes, Zhou Li, Carlos Roque D. Correia and Gerald B. Hammond Org. Biomol. Chem., 2015, 13, 9152-9167 |
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Role of Hydrogen Bonding Acceptors in Organo-Enamine Catalysis Junbin Han, Zhichao Lu, Andrew L. Flach, Robert S. Paton, Gerald B. Hammond, Bo Xu Chem Eur. J. 2015, 21, 11687-11691 |
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Potassium tris(triflyl)methide (KCTf3): a broadly applicable promoter for cationic metal catalysis Junbin Han, Zhichao Lu, Weibo Wang, Gerald B. Hammond, Bo Xu Chem Comm. 2015, 51, 13740-13743
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Supported Gold Nanoparticle-Catalyzed Hydration of Alkynes under Basic Conditions Shengzong Liang, Jacek Jasinski, Gerald B. Hammond, Bo Xu Org. Lett., 2015, 17, 162–165 |
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Efficient hydration of alkynes through acid-assisted Brønsted acid catalysis Shengzong Liang, Gerald B. Hammond, Bo Xu Chem. Commun., 2015, 51, 903-906 |
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Otome. E. Okoromoba, J. Han, G. B. Hammond, B. Xu. J. Am. Chem. Soc., 2014, 136 (41), pp 14381–14384
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“Rapid Chemical Reaction Workup Based on Rigid Solvent Extraction” B. Xu, G. B. Hammond Org. Lett. 2014,16, 5238-5241. |
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J. Han, Z. Lu, G.B. Hammond, B. Xu Eur. J. Org. Chem. 2014,2014, 5786-5792. |
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“Gold Catalyzed Synthesis of Fluorinated Tetrahydrofurans and Lactones” D. Malhotra, L. Liu, W. Wang, M. Durham, G. B. Hammond, B. Xu J. Fluorine Chem. (Special Issue ACS Award on Creative Work in Fluorine Chemistry Dr. Teruo Umemoto) 2014 |
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“Cationic Gold Catalyst Poisoning and Re-activation” M. Kumar, G. B. Hammond, B. Xu. Org. Lett.2014, 16, 3452–3455
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J. Han, N. Shimizu, Z. Lu, H. Amii,G. B. Hammond, B. Xu Org. Lett. 2014, 16, 3500–3503.
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A Highly Efficient and Broadly Applicable Cationic Gold Catalyst** Deepika Malhotra, Mark S. Mashuta, Gerald B. Hammond,* and Bo Xu* Angew. Chem. Int. Ed. DOI: 10.1002/anie.201310239 |
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Alkyne/Alkene/Allene-Induced Disproportionation of Cationic Gold(I) Catalyst Manish Kumar,[a] Jacek Jasinski,[b] Gerald B. Hammond,*[a] and Bo Xu* Chem. Eur. J. 2014, 20, 3113 – 3119
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F. Salipur, E. Merit Reyes-Reyes, B. Xu, G. B. Hammond, P. J. Bates. Free Radical Biology and Medicine,2014,68, 110-121
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Enhanced Reactivity in Homogeneous Gold Catalysis through Hydrogen Bonding Weibo Wang, Manish Kumar, Gerald B. Hammond*, and Bo Xu* Org. Lett., 2014, 16, 636-639 |
31 |
M. Kumar, M. Scobie, M. S. Mashuta, G. B. Hammond, B. Xu Org. Lett2013, 15, 724–727 |
30 |
E. Reyes-Reyes, Z. Jin, A. Vaisberg, G. B. Hammond, P. J. Bates J. Nat. Prod. 2013, 76, 2–7.
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M. Deepika, M. Mashuta, G. B. Hammond, L. Liu, Chem. Eur. J. 2013, 19, 4043-4050. |
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Synthesis of Cyclic a-Aminophosphonates through Copper Catalyzed Enamine Activation J. Han,R. S. Paton,B. Xu, G. B. Hammond Synthesis 2013,45, 463-470.
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Transition Metal Sponsored Fluorination, Difluoromethylation and Trifluoromethylation Z. Jin, B. Xu, G. B. Hammond Aldrichimica Acta2012, 45, 67- 83.
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Z. Jin, R. Hidinger, B. Xu, G.B. Hammond . J. Org. Chem.2012, 77, 7725–7729. |
25 |
Replacement of BF4- by PF6-Makes Selectfluor Greener” Z. Jin, B. Xu, G. B. Hammond, S. G. DiMagno J. Fluorine Chem. 2012,143, 226-230 |
24 |
Ligand Effects and Ligand Design in Homogeneous Gold Catalysis W. Wang, G. B. Hammond, B. Xu J. Am. Chem. Soc. 2012, 134, 5697-5705. . |
23 |
Org. Lett. 2012, 14, 1230-1233. |
22 |
Recent Advances on the Isolation and Reactivity of Organogold Complexes L. Liu and G. B. Hammond Chem. Soc. Rev. 2012, 41, 3129 - 3139. |
21 |
L. Liu, D. Malhotra, Z. Jin, R. S. Paton, K. N. Houk, and G. B. Hammond Chem. Eur. J. 2011,17, 10690-10699. . |
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Synthesis Of Fluorohydrins Through Electrophilic Fluorination Of Allyl Silanes B. Xu, W. Wang, G. B. Hammond Synthesis2011, 2383-2386. |
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B. Xu, W. Wang, G. B. Hammond J. Fluorine Chem.2011, 132, 804-810. |
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Synthesis of a-CN and a-CF3 N-Heterocycles through Tandem Nucleophilic Additions J. Han, B. Xu, G.B. Hammond Org. Lett. 2011,13, 3450-3453. . |
17 |
J. C. Aponte, Z. Jin, A. J. Vaisberg, D. Castillo, E. Málaga, W. H. Lewis, M. Sauvain, R. H. Gilman, G. B. Hammond Planta Medica2011, 77, 1597-1599.
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Construction of Cyclic Enones via Gold-Catalyzed Oxygen Transfer Reactions L. Liu, B. Xu, G. B. Hammond Beilstein J. Org. Chem.2011, 7, 606-614. |
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Copper Mediated Oxidation of Amides into Imides by Selectfluor Z. Jin, B. Xu, G. B. Hammond Tetrahedron Lett. 2011, 52, 1956-1959. |
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Synthetic Evolutions in the Nucleophilic Addition to Alkynes B. Xu, W. Wang, L. Liu, J. Han, Z. Jin and G. B. Hammond J. Organomet. Chem.2011,696, 269-276. |
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L. Liu, D. Malhotra, R. S. Paton, K. N. Houk, and G. B. Hammond Angew. Chem. Int. Ed. 2010, 49, 9132 – 9135. |
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D. Malhotra, L. Liu, G. B. Hammond Eur. J. Org. Chem. 2010, 6855-6862. |
11 |
L. Liu and G. B. Hammond Org. Lett.2010,12, 4640-4643 |
10 |
Fluorine-enabled cationic gold catalysis: Functionalized hydration of alkynes W. Wang, J. Jasinski, B. Xu, G. B. Hammond Angew. Chem. Int. Ed. 2010,49, 7247-7252. |
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From Vinylogation to Alkynylogation: Extending the Reactivity of Enolates B. Xu and G. B. Hammond Synlett Account2010 1442-1454.
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Trypanoside, Anti-Tuberculosis, Leishmanicidal and Cytotoxic Activities of TetrahydrobenzothienopyrimidinesJ. C. Aponte, A. J. Vaisberg,D. Castillo, G. Gonzalez, J. Arevalo, M. Quiliano, M. Zimic, M. Verástegui,E. Málaga, R. H. Gilman, J. M. Bustamante, R. Tarleton, Y. Wang, S.Franzblau, G. Pauli, M. Sauvain, G. B. Hammond. |
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Cytotoxic and Anti-infective Sesquiterpenes Present in Plagiochila disticha (Plagiochilaceae) and Ambrosia peruviana (Asteraceae) J. C. Aponte, H. Yang, A. J. Vaisberg, D. Castillo, E. Málaga, M. Verástegui, L. K. Casson,N. Stivers, P. J. Bates, R. Rojas, I. Fernandez, W. H. Lewis, M. Sauvain, R. H. Gilman, G. B. Hammond Planta Medica2010, 76, 705-707.
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In Vitro and In Vivo Anti-Leishmania Activity of Polysubstituted Synthetic Chalcones J. C. Aponte, D. Castillo, Y. Estevez, G. Gonzalez,J. Arevalo,G. B. Hammond, M. Sauvain Bioorg. Med. Chem. Lett.2010, 20, 100-103
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Highly efficient Cu(I)-catalyzed synthesis of N-heterocycles through a cyclization-triggered addition of alkynes. J. Han, B. Xu. G. B. Hammond J. Am. Chem. Soc. 2010, 132, 916–917. {This article was featured in Synform2010,4, A37} |
4 |
Green Synthesis of Vicinal Dithioethers and Alkenyl Thioethers from the Reaction of Alkynes and Thiols in Water Z. Jin, B. Xu, G. B. Hammond |
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L. Liu, G. B. Hammond Org. Lett. 2009,11, 5090-5092. |
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AuX3-Mediated Selective Head to Head Dimerization of Difluoropropargyl Amides S. Fustero, P. Bello, B. Fernandez, C. Del Pozo, G. B. Hammond J. Org. Chem. 2009, 74 7690–7696.
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J. C. Aponte, G. B. Hammond, B. Xu J. Org. Chem. 2009, 74, 4623–4625 |
2019, 84 (6), pp 3249–3259