Publications
University of Louisville
74. Harikrishnan, N.H.; Zamborini, F.P. “Size-dependent Electrochemical Metal Growth Kinetics.” J. Phys. Chem. C, submitted in 2022. Minor revisions requested with no additional review.
73. Mainali, B.P.; Zamborini, F.P. “Chemical Detection by Analyte-Induced Change in Electrophoretic Deposition of Gold Nanoparticles.” J. Electrochem. Soc. 2022, 169, 016504. (Special Issue dedicated to the Society for Electroanalytical Chemistry)
72. Pattadar, D.K.; Nambiar, H.N.; Allen, S.L.; Jasinski, J.B.; Zamborini, F.P. “Effect of Metal Nanoparticle Aggregate Structure on the Thermodynamics of Oxidative Dissolution.” Langmuir 2021, 37, 7320-7327.
71. Mainali, B.P.; Pattadar, D.K.; Zamborini, F.P. “Reverse Size-Dependent Electrooxidation of Gold Nanoparticles Coated with Alkanethiol Self-Assembled Monolayers (SAMs).” J. Phys. Chem. C 2021, 125, 2719-2728.
70. Pattadar, D.K.; Masitas, R.A.; Stachurski, C.D.; Cliffel, D.E.; Zamborini, F.P. “Reversing the Thermodynamics of Galvanic Replacement Reactions by Decreasing the Size of Gold Nanoparticles.” J. Am. Chem. Soc. 2020, 142, 19268-19277.
69. Mainali, B.P.; Pattadar, D.K.; Zamborini, F.P. “Size-Dependent Ripening of Gold Nanoparticles through Repetitive Electrochemical Surface Oxidation-Reduction Cycling.” J. Electrochem. Soc. 2020, 167, 146503.
68. Sibakoti, T.R.; Jasinski, J.B.; Nantz, M.H.; Zamborini, F.P. “Iodine Activation: A General Method for Catalytic Enhancement of Thiolate Monolayer-Protected Metal Clusters.” Nanoscale 2020, 12, 12027-12037.
67. Bhama, S.; Sibakoti, T.R.; Jasinski, J.B.; Zamborini, F.P. “Highly Active, Selective, and Recyclable Water-Soluble Glutathione-Stabilized Pd and Pd-Alloy Nanoparticle Catalysts in Biphasic Solvent.” ChemCatChem 2020, 12, 2253-2261.
66. Pattadar, D.K.; Mainali, B.P.; Jasinski, J.B.; Zamborini, F.P. “Electrooxidation, Size Stability, and Electrocatalytic Activity of 0.9 nm Diameter Gold Nanoclusters Coated with a Weak Stabilizer.” ChemElectroChem 2020, 7, 800-809.
65. Pattadar, D.K.; Zamborini, F.P. “Effect of Size, Coverage, and Dispersity on the Potential-Controlled Ostwald Ripening of Metal Nanoparticles.” Langmuir 2019, 35, 16416-16426.
64. Pattadar, D.K.; Sharma, J.N.; Mainali, B.P.; Zamborini, F.P. “Impact of the Assembly Method on the Surface Area-to-Volume Ratio and Electrochemical Oxidation Potential of Metal Nanospheres.” J. Phys. Chem. C. 2019, 123, 24304-24312.
63. Sibakoti, T.R.; Stinger, C.R.; Adhihetty, P.K.; Zamborini, F.P.; Nantz, M.H. “Tunable Aminooxy-Functionalized Monolayer-Protected Clusters for Nonpolar and Aqueous Oximation Reactions.” Part. Part. Syst. Char. 2019, 36, 1900093.
62. Pattadar, D.K.; Zamborini, F.P. “Halide-Dependent Dealloying of Cux/Auy Core/Shell Nanoparticles for Composition Analysis by Anodic Stripping Voltammetry.” J. Phys. Chem. C. 2019, 123, 9496-9505.
61. Qatamin, A.H.; Ghithan, J.H.; Moreno, M.; Nunn, BM; Jones, KB; Zamborini, F.P.; Keynton, R.S.; O’Toole, MG; Mendes, S.B. “Detection of Influenza Virus by Electrochemical Surface Plasmon Resonance under Potential Modulation.” Appl. Optics 2019, 58, 2839-2844.
60. Allen, S.L.; Zamborini, F.P. “Size-Selective Electrophoretic Deposition of Gold Nanoparticles Mediated by Hydroquinone Oxidation.” Langmuir, 2019, 35, 2137-2145.
59. Pattadar, D.K.; Sharma, J.N.; Mainali, B.P.; Zamborini, F.P. “Anodic Stripping Electrochemical Analysis of Metal Nanoparticles.” Curr. Opin. Electrochem. 2019, 13, 147-156. (Invited Review)
58. Pattadar, D.K.; Zamborini, F.P. “Size Stability Study of Catalytically Active Sub-2 nm Diameter Gold Nanoparticles Synthesized with Weak Stabilizers.” J. Am. Chem. Soc. 2018, 140, 14126-14133.
57. Sharma, J.N.; Pattadar, D.K.; Mainali, B.P.; Zamborini, F.P. “Size Determination of Metal Nanoparticles Based on Electrochemically Measured Surface-Area-to-Volume Ratios.” Anal. Chem. 2018, 90, 9308-9314.
56. Kharel, P.L.; Cuillier, P.M.; Fernando, K.; Zamborini, F.P.; Alphenaar, B.W. “Effect of Rare-Earth Metal Oxide Nanoparticles on the Conductivity of Nanocrystalline Titanium Dioxide: An Electrical and Electrochemical Approach.” J. Phys. Chem. C. 2018, 122, 15090-15096.
55. Kharel, P.L.; Zamborini, F.P.; Alphenaar, B.W. “Enhancing the Photovoltaic Performance of Dye-Sensitized Solar Cells with Rare Earth Metal Oxide Nanoparticles.” J. Electrochem. Soc. 2018, 165, H52-H56.
54. Allen, S.L; Sharma, J.N.; Zamborini, F.P. “Aggregation-Dependent Oxidation of Metal Nanoparticles.” J. Am. Chem. Soc. 2017, 139, 12895-12898.
53. Masitas, R.A.; Allen, S.L.; Zamborini, F.P. “Size-Dependent Electrophoretic Deposition of Catalytic Gold Nanoparticles.” J. Am. Chem. Soc. 2016, 138, 15295-15298.
52. Yang, Y.; Cornwell, L.B.; Ibañez, F.J.; Zamborini, F.P. “Chemiresistor Arrays Prepared by Simple and Fast Vapor-Phase Thiol Place-Exchange Functionalization of Gold Monolayer-Protected Films.” ChemElectroChem 2016, 3, 1230-1236.
51. Luitel, T.; Fernando, K.; Tatum, B.S.; Alphenaar, B.W.; Zamborini, F.P. “Increased Efficiency of Dye-Sensitized Solar Cells by Addition of Rare Earth Oxide Microparticles into a Titania Acceptor.” Electrochim. Acta 2016, 211, 918-925.
50. Dasari, R.; Zamborini, F.P. “Surface Enhanced Raman Spectroscopy at Electrochemically Fabricated Silver Nanowire Junctions” Anal. Chem. 2016, 88, 675-681.
49. Shah, N.; Zamborini, F.P. “Surfactant-Assisted, Voltage-Driven Silver Nanoparticle Chain Formation across Microelectrode Gaps in Air” ACS Nano 2015, 9, 10278-10286.
48. Fang, A.; White, S.; Masitas, R.A.; Zamborini, F.P.; Jain, P.K. “One-to-One Correlation between Structure and Optical Response in a Heterogeneous Distribution of Plasmonic Constructs” J. Phys. Chem. C 2015, 119, 24086-24094.
47. Fang, A.; White, S.; Jain, P.K.; Zamborini, F.P. “Regioselective Plasmonic Coupling in Metamolecular Analogs of Benzene” Nano Lett 2015, 15, 542-548.
46. Masitas, R.A.; Khachian, I.V.; Bill, B.L.; Zamborini, F.P. “Effect of Surface Charge and Electrode Material on the Size-Dependent Oxidation of Surface-Attached Metal Nanoparticles” Langmuir 2014, 30, 13075-13084.
45. Chauhan, R.; Moreno, M.; Banda, D.M.; Zamborini, F.P.; Grapperhaus, C.A. “Chemiresistive Metal-Stabilized Thiyl Radical Films as Highly Selective Ethylene Sensors” RSC Adv. 2014, 4, 46787-56790.
44. Pandit, B.; Luitel, T.; Cummins, D.R.; Thapa, A.K.; Druffel, T.; Zamborini, F.; Liu, J. “Spectroscopic Investigation of Photoinduced Charge-Transfer Processes in FTO/TiO2/N719 Photoanodes with and without Covalent Attachment through Silane-Based Linkers” J. Phys. Chem. A 2013, 117, 13513-13523.
43. Luitel, T.; Zamborini, F.P. “Covalent Modification of Photoanodes for Stable Dye-Sensitized Solar Cells” Langmuir 2013, 29, 13582-13594.
42. Moreno, M.; Kissell, L.N.; Jasinski, J.B.; Zamborini, F.P. “Selectivity and Reactivity of Alkylamine- and Alkanethiolate-Stabilized Pd and PdAg Nanoparticles for Hydrogenation and Isomerization of Allyl Alcohol” ACS Catal. 2012, 2, 2602-2613.
41. Masitas, R.A.; Zamborini, F.P. “Oxidation of Highly Unstable <4 nm Diameter Gold Nanoparticles 800 mV Negative of the Bulk Oxidation Potential” J. Am. Chem. Soc. 2012, 134, 5014-5017.
40. Zamborini, F.P.; Bao, L.; Dasari, R.. “Nanoparticles in Measurement Science” Anal. Chem. 2012, 84, 541-576
39. Sidorov, A.; Slawinski, G.W.; Sumanasekera, G.U.; Zamborini, F.P. “Surface-Enhanced Raman Spectroscopy Study of Thin Graphene Sheets Functionalized with Gold and Silver Nanorods by Seed-Mediated Growth” Carbon 2012, 50, 699-705.
38. Ibañez, F.J.; Zamborini, F.P. “Chemiresistive Sensing with Chemically-Modified Metal and Alloy Nanoparticles” Small 2012, 8, 174-202.
37. Slawinski, G.W.; Ivanova, O.S.; Zamborini, F.P. “Twin Plane Decoration of Silver Nanorods with Palladium by Galvanic Exchange at a Controlled Rate” Langmuir 2011, 27, 13293-13301.
36. Dasari, R.; Ibañez, F.J.; Zamborini, F.P. “Electrochemical Fabrication of Metal/Organic/Metal Junctions for Molecular Electronics or Sensing Applications” Langmuir 2011, 27, 7285-7293. (highlighted on the cover).
35. Beeram, S.R.; Zamborini, F.P. “Effect of Protein Binding Coverage, Location, and Distance on the Localized Surface Plasmon Resonance Response of Purified Au Nanoplates Grown Directly on Surfaces” J. Phys. Chem. 2011, 115, 7364-7371.
34. M. Moreno; Ibañez, F.J.; Jasinski, J.B.; Zamborini, F.P. “Hydrogen Reactivity of Pd Nanoparticles Coated with Mixed Monolayers of Alkyl Thiols and Alkyl Amines for Sensing and Catalysis Applications” J. Am. Chem. Soc. 2011, 133, 4389-4397.
33. Abdelmoti, L.G.; Zamborini, F.P., “Potential-Controlled Electrochemical Seed-Mediated Growth of Gold Nanorods Directly on Electrode Surfaces” Langmuir 2010, 26, 13511-13521.
32. Beeram, S.R.; Zamborini, F.P. “Purification of Gold Nanoplates Grown Directly on Surfaces for Enhanced Localized Surface Plasmon Resonance Biosensing” ACS Nano 2010, 4, 3633-3646.
31. Ivanova, O.S.; Zamborini, F.P. “Electrochemical Size Discrimination of Gold Nanoparticles Attached to Glass/Indium-Tin-Oxide Electrodes by Oxidation in Bromide-Containing Electrolyte” Anal. Chem. 2010, 82, 5844-5850.
30. Ivanova, O.S.; Zamborini, F.P. “Size-Dependent Electrochemical Oxidation of Silver Nanoparticles” J. Am. Chem. Soc. 2010, 132, 70-72.
29. Beeram, S.R.; Zamborini, F.P. “Selective Attachment of Antibodies to the Edges of Gold Nanostructures for Enhanced Localized Surface Plasmon Resonance Biosensing” J. Am. Chem. Soc. 2009, 131, 11689-11691.
28. Dasari, R.; Zamborini, F.P. “Hydrogen Switches and Sensors Fabricated by Combining Electropolymerization and Pd Electrodeposition at Microgap Electrodes” J. Am. Chem. Soc. 2008, 130, 16138-16139.
27. Ibañez, F.J.; Zamborini, F.P. “Chemiresistive Sensing of Volatile Organic Compounds with Films of Surfactant-Stabilized Gold and Gold-Silver Alloy Nanoparticles” ACS Nano 2008, 2, 1543-1552.
26. Ibañez, F.J.; Zamborini, F.P. “The Reactivity of Hydrogen with Solid-State Films of
Alkylamine- and Tetraoctylammonium Bromide-Stabilized Pd, PdAg, and PdAu
Nanoparticles for Sensing and Catalysis Applications" J. Am. Chem. Soc. 2008, 130, 622-633.
25. Slawinski, G.W.; Zamborini, F.P. “Synthesis and Alignment of Silver Nanorods and Nanowires and the Formation of Pt, Pd, and Core/Shell Structures by Galvanic Exchange Directly on Surfaces” Langmuir 2007, 23, 10357-10365.
24. Mieszawski, A.J.; Jalilian, R.; Sumanasekera, G.U.; Zamborini, F.P. “The Synthesis and Fabrication of One-Dimensional Nanoscale Heterojunctions” Small 2007, 3, 722-756.
23. Ibañez, F.J.; Zamborini, F.P. “Ozone- and Thermally-Activated Films of Palladium Monolayer-Protected Clusters for Chemiresistive Hydrogen Sensing”, Langmuir 2006, 22, 9789-9796.
22. Mieszawska, A.J.; Slawinski, G.W.; Zamborini, F.P. “Directing the Growth of Highly-Aligned Gold Nanorods by a Surface Chemical Amidation Reaction” J. Am. Chem. Soc. 2006, 128, 5622-5623.
21. Ibañez, F.J.; Gowrishetty, U.; Crain, M.M.; Walsh, K.M.; Zamborini, F.P. “Chemiresistive Vapor Sensing with Microscale Films of Gold Monolayer Protected Clusters” Anal. Chem. 2006, 78, 753-761.
20. Mieszawska, A.J.; Jalilian, R.; Sumanasekera, G.U.; Zamborini, F.P. “Synthesis of Gold Nanorod/Single Wall Carbon Nanotube Heterojunctions Directly on Surfaces” J. Am. Chem. Soc. 2005, 127, 10822-10823.
19. Mieszawska, A.J.; Zamborini, F.P. “Gold Nanorods Grown Directly on Surfaces from Microscale Patterns of Gold Seeds” Chem. Mater. 2005, 17, 3415-3420.
18. Wei, Z.; Zamborini, F.P. “Directly Monitoring the Growth of Gold Nanoparticle Seeds into Gold Nanorods” Langmuir 2004, 20, 11301-11304.
17. Wei, Z.; Mieszawska, A.J.; Zamborini, F.P. “Synthesis and Manipulation of High Aspect Ratio Gold Nanorods Grown Directly on Surfaces” Langmuir 2004, 20, 4322-4326.
16. Zamborini, F.P.; Smart, L.E.; Leopold, M.C.; Murray, R.W. “Distance-Dependent Electron Hopping Conductivity and Nanoscale Lithography of Chemically-Linked Gold Monolayer Protected Cluster Films” Anal. Chim. Acta. 2003, 496, 3-16.
University of North Carolina at Chapel Hill (Postdoctoral Research Associate)
15. Leopold, M.C.; Donkers, R.L.; Georganopoulou, D.; Fisher, M.; Zamborini, F.P.; Murray, R.W. “Growth, Conductivity, and Vapor Response Properties of Metal Ion-Carboxylate Linked Nanoparticle Films” Faraday Discuss. 2003, 125, 63-76.
14. Zamborini, F.P.; Leopold, M.C.; Hicks, J.F.; Kulesza, P.J.; Malik, M.A.; Murray, R.W. “Electron Hopping Conductivity and Vapor Sensing Properties of Flexible Network Polymer Films of Metal Nanoparticles” J. Am. Chem. Soc. 2002, 124, 8958-8964.
13. Hicks, J.F.; Zamborini, F.P.; Murray, R.W. “Dynamics of Electron Transfers Between Electrodes and Monolayers of Nanoparticles” J. Phys. Chem. B. 2002, 106, 7751-7757.
12. Hicks, J.F.; Zamborini, F.P.; Osisek, A.J.; Murray, R.W. “The Dynamics of Electron Self-Exchange Between Nanoparticles” J. Am. Chem. Soc. 2001, 123, 7048-7053.
11. Zamborini, F.P.; Gross, S.M.; Murray, R.W. “Synthesis, Characterization, Reactivity, and Electrochemistry of Palladium Monolayer Protected Clusters (MPCs).” Langmuir 2001, 17, 481-488.
10. Wuelfing, W.P.; Zamborini, F.P.; Templeton, A.C.; Wen, X.; Yoon, H.; Murray R.W. “Monolayer Protected Clusters: Molecular Precursors to Metal Films.” Chem. Mater. 2001, 13, 87-95.
9. Cliffel, D.E.; Zamborini, F.P.; Gross, S.M.; Murray, R.W. “Mercaptoammonium Monolayer-Protected, Water-Soluble Gold, Silver, and Palladium Clusters.” Langmuir 2000, 16, 9699-9702.
8. Templeton, A.C.; Zamborini, F.P.; Wuelfing, W.P.; Murray, R.W. “Controlled and Reversible Formation of Nanoparticle Aggregates and Films Using Cu2+-Carboxylate Chemistry.” Langmuir 2000, 16, 6682-6688.
7. Zamborini, F.P.; Hicks, J.F.; Murray, R.W. “Quantized Double Layer Charging of Nanoparticle Films Assembled Using Carboxylate/(Cu2+ or Zn2+)/Carboxylate Bridges.” J. Am. Chem. Soc. 2000, 122, 4514-4515.
Texas A&M University (Graduate Student)
6. Baker, L.A.; Zamborini, F.P.; Sun, L.; Crooks, R.M. “Dendrimer-Mediated Adhesion Between Vapor-Deposited Au and Glass or Si Wafers.” Anal. Chem. 1999, 71, 4403-4406.
5. Zamborini, F.P.; Crooks, R.M. “Nanometer-Scale Patterning of Metals by Electrodeposition from an STM Tip in Air.” J. Am. Chem. Soc. 1998, 120, 9700-9701.
4. Zamborini, F.P.; Crooks R.M. “Corrosion Passivation of Gold by n-Alkanethiol Self-Assembled Monolayers: Effect of Chain Length and End Group.” Langmuir 1998, 14, 3279-3286.
3. Zamborini, F.P.; Campbell, J.K.; Crooks, R.M. “Spectroscopic, Voltammetric, and Electrochemical Scanning Tunneling Microscopic Study of Underpotentially Deposited Cu Corrosion and Passivation with Self-Assembled Organomercaptan Monolayers.” Langmuir 1998, 14, 640-647.
2. Zamborini, F.P.; Crooks, R.M. “In-Situ Electrochemical Scanning Tunneling Microscopy (ECSTM) Study of Cyanide-Induced Corrosion of Naked and Hexadecyl Mercaptan-Passivated Au(111).” Langmuir 1997, 13, 122-126.
1. Schoer, J.K.; Zamborini, F.P.; Crooks, R.M. “Scanning Probe Lithography. 3. Nanometer-Scale Electrochemical Patterning of Au and Organic Resists in the Absence of Intentionally Added Solvents or Electrolytes.” J. Phys. Chem. 1996, 100, 11086-11091.