ChE 594 Special Topics: Chemical Vapor Deposition

                                                                                               

      1998‑2000 Catalog Data:            ChE 594 Special Topics in Chemical Engineering.  Credits 3.

      Prerequisites by Topic:

Undergraduate or Graduate Thermodynamics

Undergraduate Reactor Design

Undergraduate or Graduate Transport Phenomena

Undergraduate Course on Materials Science

     Textbooks: No prescribed textbook. Class notes chapters from several books and handouts.        

    Course Objectives:          Following this course students will:

Understand the concepts involved in the deposition of thin and thick films using various Chemical Vapor Deposition (CVD) methods.

Apply chemical kinetics (gas phase, gas-solid and plasma), thermodynamics and transport concepts to understand and design the chemical vapor deposition process.

Understand the nucleation and growth aspects of the vapor grown films, thin and thick film science.

    Topics Covered:

Overall review of various CVD Systems and vacuum environments

Thermodynamic principles involved with gas phase and gas-solid systems in CVD reactors

Chemical kinetics of gas phase and gas-solid reactions

Chemistry of plasma systems

Transport considerations in CVD reactors

Thin and thick films science

Stresses in Films

Single crystal surfaces and epitaxy

Nucleation, Growth & Morphology

Texturing of polycrystalline films

Role of defects during growth and on the film properties

Laboratory assignments using CHEMKIN III & SAMPR programs (Licensed from Reaction Design, Inc. & NASA)

Equilibrium analysis of gas phase reactions and gas-solid reactions

Sensitivity and steady state analysis

Modeling of plasma gas phase chemistry

Written term paper in a proposal format

   Class Schedule: Two lecture sessions per week, each of 75 minutes duration.

  Contribution of course to meeting the professional component:

Fifth year and graduate elective course

Applications of chemical kinetics & transport processes to vapor phase materials synthesis

Focus on practical applications of CVD reactors, processes, electronic & amorphous materials