2006 to 2010

IC2010

"Controlled Sulfur Oxygenation of the Ruthenium Dithiolate (4,7-Bis-(2′-methyl-2′-mercaptopropyl)-1-thia-4,7-diazacyclononane)RuPPh3 under Limiting O2 Conditions Yields Thiolato/Sulfinato, Sulfenato/Sulfinato, and Bis-Sulfinato Derivatives."
Masitas, C. A.; Kumar, M.; Mashuta, M. S.; Kozlowski, P. M.; Grapperhaus, C. A.
Inorg. Chem. 2010, 49, 10875-10881.

"Synthesis, Structure, and Solution Properties of [(mim-TASN)FeCl2]+ and Its μ-Oxo Derivative."
Cui, J.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus, C. A.
Inorg. Chem. 2010, 49, 10427-10435.

"Asymmetric Oxygenation of a Ruthenium Dithiolate Mimics the Mixed Sulfenato/Sulfinato Donor Sets of Nitrile Hydratase and Thiocyanate Hydrolase."
Masitas, C. A.; Mashuta, M. S.; Grapperhaus, C. A.
Inorg. Chem. 2010, 49, 5344-5346.

"Supramolecular Assembly of a Dinuclear Ag(I) Complex with Discreet Ag2S2 Centers."
Grapperhaus, C. A.; Cui, J.; Buchanan, R. M.; Mashuta, M. S.
Inorg. Chem. Comm. 2009, 12, 1091-1093.

"Synthesis and Sulfur Oxygenation of a (N3S)Ni Complex Related to Nickel-Containing Superoxide Dismutase."
Mullins, C. S.; Grapperhaus, C. A.; Frye, B. C.; Wood, L. H.; Hay, A. J.; Buchanan, R. M.; Mashuta, M. S.
Inorg. Chem. 2009, 48, 9974-9976.

"N2S3X-Fe Models of Nitrile Hydratase."
O'Toole, M. G.; Grapperhaus, C. A.
In Bioinorganic Chemistry, American Chemical Society: Washington DC, 2009, 99-113.


JACS2009

"Substrate Binding Preferences and pKa Determinations of a Nitrile Hydratase Model Complex: Variable Solvent Coordination to [(bmmp-TASN)Fe]OTf."
O'Toole, M. G.; Bennett, B.; Mashuta, M. S.; Grapperhaus, C. A.
Inorg. Chem. 2009, 48, 2300-2308.

"Redox-Regulated Ethylene Binding to a Rhenium-Thiolate Complex."
Grapperhaus, C. A.; Ouch, K.; Mashuta, M. S.
J. Am. Chem. Soc.
2009, 131, 64-65.

"Spin-State-Dependent Oxygen Sensitivity of Iron Dithiolates: Sulfur Oxygenation or Disulfide Formation."
O'Toole, M. G.; Kreso, M.; Kozlowski, P. M.; Mashuta, M. S.; Grapperhaus, C. A.
J. Biol. Inorg. Chem.
2008, 13, 1219-1230.

"Hg(II) and Cd(II) Complexes with Mixed Donor Macrocyclic Thioethers: The Oxophobicity of Mercury(II)."
Grant, G. J.; Botros, M. E.; Hassler, J. S.; Janzen, D. E.; Grapperhaus, C. A.; O'Toole, M. G.; VanDerveer, D. G.
Polyhedron
2008, 27, 3097-3104.

 

JBIC2008

"An Experimental and Computational Study of Sulfur-Modified Nucleophilicity in a Dianionic NiN2S2 Complex."
Green, K. N.; Brothers, S. M.; Jenkins, R. M.; Carson, C. E.; Grapperhaus, C. A.; Darensbourg, M. Y.
Inorg. Chem.
2007, 46, 7536-7544.

"Carbon-Sulfur Bond Formation via Alkene Addition to an Oxidized Ruthenium Thiolate."
Grapperhaus, C. A.; Venna, K. B.; Mashuta, M. S.
Inorg. Chem.
2007, 46, 8044-8050.

"{3,3 '-[Ethane-1,2-diylbis(methylimino)]-bis(propane-1-thiolato)}nickel(II)."
Grapperhaus, C. A.; O'Toole, M. G.; Mashuta, M. S.
Acta Cryst. Section E
2007, 63, M2281-U317.

"Singlet Diradical Character of an Oxidized Ruthenium Trithiolate: Electronic Structure and Reactivity."
Grapperhaus, C. A.; Kozlowski, P. M.; Kumar, D.; Frye, H. N.; Venna, K. B.; Poturovic, S.
Angew. Chem., Int. Ed. Engl.
2007, 46, 4085-4088.

 

 

ICC2006

"Density Functional Theory Investigations of NiN2S2 Reactivity as a Function of Nitrogen Donor Type and N-H...S Hydrogen Bonding Inspired by Nickel-Containing Superoxide Dismutase."
Mullins, C. S.; Grapperhaus, C. A.; Kozlowski, P. M.
J. Biol. Inorg. Chem.
2006, 11, 617-625.

"Synthesis and Structure of the Tetradeca-Iron(III) Oxide-Alkoxide Cluster [Bu4N]2[Fe14O8(OCH2CH3)20Cl8]."
Grapperhaus, C. A.; O'Toole, M. G.; Mashuta, M. S.
Inorg. Chem. Comm.
2006, 9, 1204-1206.

"Ethyl 1-methylimidazole-2-carboxylate."
Frye, B. C.; Mashuta, M. S.; Mullins, C. S.; Grapperhaus, C. A.; Buchanan, R. M.
Acta Cryst. Section E
2006, 62, O1548-O1549.