1996 to 2000

Grapperhaus Publications 1996-2000

IC2000

"Mononuclear (nitrido)iron(V) and (oxo)iron(IV) complexes via photolysis of [(cyclam-acetato)FeIII(N3)]+ and ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in water/acetone mixtures."
Grapperhaus, C. A.; Mienert, B.; Bill, E.; Weyhermuller, T.; Wieghardt, K.
Inorg. Chem.
2000, 39, 5306-5317.

"Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis-dithiolate (bme*-daco)Ni."
Bellefeuille, J. A.; Grapperhaus, C. A.; Derecskei-Kovacs, A.; Reibenspies, J. H.; Darensbourg, M. Y.
Inorg. Chim. Acta
2000, 300, 73-81.

"Ozone oxidation of iron(III) in a monofunctionalized cyclam: Spectroscopic characterization of high valent iron species."
Grapperhaus, C. A.; Bill, E.; Wieghardt, K.
J. Inorg. Biochem.
1999, 74, 146-146.

"Synthesis and dimer cleavage reactions of the N2S thiolate bridged dimer [(mmp-dach)2Ni2]Cl2."
Grapperhaus, C. A.; Bellefeuille, J. A.; Reibenspies, J. H.; Darensbourg, M. Y.
Inorg. Chem.
1999, 38, 3698-3703.

"Methylation of tethered thiolates in [(bme-daco)Zn]2 and [(bme-daco)Cd]2 as a model of zinc sulfur-methylation proteins."
Grapperhaus, C. A.; Tuntulani, T.; Reibenspies, J. H.; Darensbourg, M. Y.
Inorg. Chem.
1998, 37, 4052-4058.

ACC1998

"Oxygen capture by sulfur in nickel thiolates."
Grapperhaus, C. A.; Darensbourg, M. Y.
Acc. Chem. Res.
1998, 31, 451-459.

"Alkylation-induced O-atom rearrangement in nickel S-oxygenates."
Bellefeuille, J. A.; Grapperhaus, C. A.; Buonomo, R. M.; Reibenspies, J. H.; Darensbourg, M. Y.
Organometallics
1998, 17, 4813-4821.

"Singlet oxygen and the production of sulfur oxygenates of nickel(II) and palladium(II) thiolates."
Grapperhaus, C. A.; Maguire, M. J.; Tuntulani, T.; Darensbourg, M. Y.
Inorg. Chem.
1997, 36, 1860-1866.

"Template effect for O2 addition across cis-sulfur sites in nickel dithiolates."
Grapperhaus, C. A.; Darensbourg, M. Y.; Sumner, L. W.; Russell, D. H.
J. Am. Chem. Soc.
1996, 118, 1791-1792.

JACS1996