Recent Publications

Recent Publications (2011-current)

ICC2013

 

"Reinvestigation of the first structurally characterized metal-coordinated sulfenic acid complex"
Chauhan, R.; Mashuta, M. S.; Grapperhaus, C. A. 
Inorg. Chem. Commun. 2013, 37, 186-188


"Addition of polysubstituted alkenes, aromatic alkynes, and dienes to a metal-stabilized thiyl radical via carbon-sulfur bond formation: Electrochemical, chemical, and computational investigations"
Sampson, K. O.; Kumar, D.; Mashuta, M. S.; Grapperhaus, C. A.  
Inorg. Chim. Acta 2013, 408, 1-8

 

"Probing the Reactivity and Radical Nature of Oxidized Transition Metal-Thiolate Complexes by Mass Spectrometry"
Lu, M.; Campbell, J. L.; Chauhan, R.; Grapperhaus, C. A. ; Chen, H. 
J. Am. Soc. Mass. Spec. 2013, 24, 502-512

 

 

ChemComm2013

 

"Bioinspired catalytic nitrile hydration by dithiolato, sulfinato/thiolato, and sulfenato/sulfinato ruthenium complexes"
Kumar, D.; Masitas, C. A.; Tran, T. N.; Grapperhaus, C. A. 
Chem. Commun. 2013, 294–296

"Selective and Reversible Base-Induced Elimination of a Ruthenium Dithioether Yields a Vinyl Metallosulfonium Complex"
Chauhan, R.; Mashuta, M. S.; Grapperhaus, C. A. 
Inorg. Chem. 2012, 51, 7913–7920

"Influence of Sequential Thiolate Oxidation on a Nitrile Hydratase Mimic Probed by Multiedge X-ray Absorption Spectroscopy"
Shearer, J.; Callant, P. E.; Masistas, C. A.; Grapperhaus, C. A. 
Inorg. Chem. 2012, 51, 6032-6045

"Alkyne addition to a metal-stabilized thiyl radical: Carbon-sulfur bond formation between 1-octyne and [Ru(SP)3]+"
Ouch, K.; Mashuta, M. S.; Grapperhaus, C. A. 
Eur. J. Inorg. Chem. 2012, 475-478

"Kinetic study of nickel-thiolate oxygenation by hydrogen peroxide. Implications for nickel-containing superoxide dismutase"
Herdt, D. R.; Grapperhaus, C. A.
Dalton Trans.
2012, 41, 364-366


"N-(2-formyl-1-methylimidazol-4-yl)-2,2-dimethylpropanamide: A versatile reagent for preparing imidazole-amine ligands with variable second-coordination spheres"
Cheruzel, L. E.; Cui, J. L.; Mashuta, M. S.; Grapperhaus, C. A.; Buchanan, R. M. 
Tetrahedron Lett. 2011, 52, 4771-4774

"Metal-Stabilized Thiyl Radicals as Scaffolds for Reversible Alkene Addition via C-S Bond Formation/Cleavage"
Ouch, K.; Mashuta, M. S.; Grapperhaus, C. A.
Inorg. Chem. 2011, 50, 9904–9914.