Table 1 Common chemicals that form explosive levels of peroxides and their storage limits
| Form potentially explosive peroxides without concentration (a). Dispose or test 3 months after opening. |
Form potentially explosive peroxides on concentration (b). Dispose or test 12 months after opening. |
Autopolymerize as a result of peroxide accumulation. Dispose or test inhibited materials after 12 months. |
|---|---|---|
| Butadiene (c) | Acetal | Acrylic acid |
| Chloroprene (d) | Acetaldehyde | Acrylonitrile |
| Divinyl acetylene | Benzyl alcohol |
Butadienee |
| Chloroprene | Isopropyl ether |
2-butanol |
| Tetrafluoroethylene (c) | Cyclohexanol | Chlorotrifluoroethylene |
| Vinylidene chloride | 2-cyclohexen-1-ol |
Methyl |
| Methacrylate | Cumene | Stryene |
| Tetrafluoroethylene | Decahydronaphthalene | Vinyl acetate |
| Diacetylene | Vinyl acetylene | |
| Dicyclopentadiene | Vinyl chloride | |
| Diethyl ether |
Vinyl pyridine | |
| Diethylene glycol |
||
| Dimethyl ether |
||
| Dioxanes | ||
| Ethylene glycol dimethyl ether |
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| 4-heptanol |
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| Methyl acetylene |
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| Methyl isobutyl ketone |
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| 3-methyl-1 butanol |
||
| Methyl cyclopentane |
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| 2-pentanol |
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| 4-penten-1-ol |
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| 1-phenylethanol |
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| 2-phenylethanol |
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| 2-propanol (isoproranol, "IPA") |
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| Tetrahydrofuran |
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| Tetrahydronaphthalene |
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| Vinyl ethers |
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| Other secondary alcohols |
(a) Store under nitrogen, if practical.
(b) WARNING! May become unstable if concentrated intentionally or accidentally by user.
(c) When stored as an inhibited liquid monomer.
(d) When stored as a liquid monomer.
(e) When stored as a gas.
R.J. Kelly, “Review of Safety Guidelines for peroxide-forming Organic Chemicals”, Chemical Health & Safety, September/October 1996, pp 28-36.
last modified
2007-08-16 07:54