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Craig A. Grapperhaus

Professor

Craig A. Grapperhaus
Division: Inorganic Chemistry
Specialty: Metal-thiolates, ligand-based reactivity, inorganic synthesis
Phone: 502-852-5932
Email: grapperhaus@louisville.edu
Website: Grapperhaus Research Group

Education and Research Experience

1994 B.S.   Southern Illinois University at Edwardsville
1998 Ph.D. Texas A&M University
1998-2000 Alexander von Humboldt Postdoctoral Fellow Max-Planck Institut für Strahlenchemie

Research Interests

See website.

Publications (see group website for most up to date list)

"Metal-Stabilized Thiyl Radicals as Scaffolds for Reversible Alkene Addition via C-S Bond Formation/Cleavage"
Ouch, K.; Mashuta, M. S.; Grapperhaus, C. A.
Inorg. Chem.  2011, 50, ASAP.

"Controlled Sulfur Oxygenation of the Ruthenium Dithiolate (4,7-Bis-(2′-methyl-2′-mercaptopropyl)-1-thia-4,7-diazacyclononane)RuPPh3 under Limiting O2 Conditions Yields Thiolato/Sulfinato, Sulfenato/Sulfinato, and Bis-Sulfinato Derivatives."
Masitas, C. A.; Kumar, M.; Mashuta, M. S.; Kozlowski, P. M.; Grapperhaus, C. A.
Inorg. Chem.  2010, 49, 10875-10881.

"Synthesis, Structure, and Solution Properties of [(mim-TASN)FeCl2]+ and Its μ-Oxo Derivative."
Cui, J.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus, C. A.
Inorg. Chem.  2010, 49, 10427-10435.

"Asymmetric Oxygenation of a Ruthenium Dithiolate Mimics the Mixed Sulfenato/Sulfinato Donor Sets of Nitrile Hydratase and Thiocyanate Hydrolase."
Masitas, C. A.; Mashuta, M. S.; Grapperhaus, C. A.
Inorg. Chem.  2010, 49, 5344-5346.

"Supramolecular Assembly of a Dinuclear Ag(I) Complex with Discreet Ag2S2 Centers."
Grapperhaus, C. A.; Cui, J.; Buchanan, R. M.; Mashuta, M. S.
Inorg. Chem. Comm. 2009, 12, 1091-1093.

"Synthesis and Sulfur Oxygenation of a (N3S)Ni Complex Related to Nickel-Containing Superoxide Dismutase."
Mullins, C. S.; Grapperhaus, C. A.; Frye, B. C.; Wood, L. H.; Hay, A. J.; Buchanan, R. M.; Mashuta, M. S.
Inorg. Chem. 2009, 48, 9974-9976.

"N2S3X-Fe Models of Nitrile Hydratase."
O'Toole, M. G.; Grapperhaus, C. A.
In Bioinorganic Chemistry, American Chemical Society: Washington DC, 2009, 99-113.

"Substrate Binding Preferences and pKa Determinations of a Nitrile Hydratase Model Complex: Variable Solvent Coordination to [(bmmp-TASN)Fe]OTf."
O'Toole, M. G.; Bennett, B.; Mashuta, M. S.; Grapperhaus, C. A.
Inorg. Chem. 2009, 48, 2300-2308.

"Redox-Regulated Ethylene Binding to a Rhenium-Thiolate Complex."
Grapperhaus, C. A.; Ouch, K.; Mashuta, M. S.
J. Am. Chem. Soc.
2009, 131, 64-65.

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